全文获取类型
收费全文 | 1875篇 |
免费 | 281篇 |
国内免费 | 189篇 |
专业分类
化学 | 1384篇 |
晶体学 | 22篇 |
力学 | 116篇 |
综合类 | 15篇 |
数学 | 199篇 |
物理学 | 609篇 |
出版年
2024年 | 3篇 |
2023年 | 49篇 |
2022年 | 28篇 |
2021年 | 61篇 |
2020年 | 115篇 |
2019年 | 92篇 |
2018年 | 67篇 |
2017年 | 59篇 |
2016年 | 113篇 |
2015年 | 89篇 |
2014年 | 103篇 |
2013年 | 150篇 |
2012年 | 165篇 |
2011年 | 194篇 |
2010年 | 103篇 |
2009年 | 96篇 |
2008年 | 127篇 |
2007年 | 108篇 |
2006年 | 66篇 |
2005年 | 63篇 |
2004年 | 53篇 |
2003年 | 56篇 |
2002年 | 60篇 |
2001年 | 62篇 |
2000年 | 45篇 |
1999年 | 44篇 |
1998年 | 23篇 |
1997年 | 25篇 |
1996年 | 18篇 |
1995年 | 11篇 |
1994年 | 16篇 |
1993年 | 11篇 |
1992年 | 13篇 |
1991年 | 6篇 |
1990年 | 11篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有2345条查询结果,搜索用时 14 毫秒
61.
62.
Tailorable PC71BM Isomers: Using the Most Prevalent Electron Acceptor to Obtain High‐Performance Polymer Solar Cells
下载免费PDF全文
Xin‐Xing Zhan Xin Zhang Si‐Min Dai Shu‐Hui Li Xu‐Zhai Lu Dr. Lin‐Long Deng Prof. Su‐Yuan Xie Prof. Rong‐Bin Huang Prof. Lan‐Sun Zheng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(52):18709-18713
Despite being widely used as electron acceptor in polymer solar cells, commercially available PC71BM (phenyl‐C71‐butyric acid methyl ester) usually has a “random” composition of mixed regioisomers or stereoisomers. Here PC71BM has been isolated into three typical isomers, α‐, β1‐ and β2‐PC71BM, to establish the isomer‐dependent photovoltaic performance on changing the ternary composition of α‐, β1‐ and β2‐PC71BM. Mixing the isomers in a ratio of α/β1/β2=8:1:1 resulted in the best power conversion efficiency (PCE) of 7.67 % for the polymer solar cells with PTB7:PC71BM as photoactive layer (PTB7=poly[[4,8‐bis[(2‐ethylhexyl)oxy]benzo[1,2‐b:4,5‐b′]dithiophene‐2,6‐diyl][3‐fluoro‐2‐[(2‐ethylhexyl)carbonyl]thieno[3,4‐b]thiophenediyl]]). The three typical PC71BM isomers, even though sharing similar LUMO energy levels and light absorption, render starkly different photovoltaic performances with average‐performing PCE of 1.28–7.44 % due to diverse self‐aggregation of individual or mixed PC71BM isomers in the otherwise same polymer solar cells. 相似文献
63.
64.
65.
66.
Yan-Yan Si Lu-Jun Liang Shan Tang Yun-Kun Qi Yong Huang Ji-Shen Zheng 《Tetrahedron letters》2018,59(3):268-271
Protein chemical synthesis can provide the homogeneous atypical ubiquitin chains that are usually difficult to obtain by other methods. Herein, we report a new one-pot ligation approach for the synthesis of atypical Ub chains based on the Tfacm-protected isoUb building block with operational simplicity and high efficiency. The key intermediate, the Tfacm-protected isoUb building block can be readily prepared by Fmoc SPPS. The practicality and efficiency of the new method is demonstrated by the successful preparation of K11-linked di-Ub. 相似文献
67.
Mingli Jiao Kai Yang Wangxi Zhang Wei Pan Ruiwen Zhang Si Xie 《Journal of Macromolecular Science: Physics》2013,52(11):2103-2115
A series of poly(L-lactic acid)/polybutadiene (PLA/PB) biodegradable multiblock elastomers was synthesized and characterized. A two-step process to prepare PLA/PB multiblock elastomers was applied. Melt polymerization was used to prepare poly(L-lactic acid) (PLA) terminated with hydroxyl groups and, at the same time, hydroxyl-terminated polybutadiene (HTPB) and 1,6-hexamethylene diisocyanate (HDI) were employed to synthesize diisocyanate-terminated polybutadiene (ITPB). Then, PLA and ITPB were reacted with different PLA/PB weight ratios. Consequently, a series of PLA/PB biodegradable poly(ester-urethane)s with crosslinked chains was obtained. Swelling characteristics and crosslink density of the crosslinked elastomer were investigated. DMA was applied to characterize its thermal properties. The measurement of mechanical properties showed that a PLA/PB elastomer with adjustable mechanical properties was synthesized. Micromorphology, hydrophobicity, and degradability of the material were also characterized. 相似文献
68.
69.
Si Zhong Zhou 《数学学报(英文版)》2014,30(1):181-186
LetG be a graph,and k≥2 be a positive integer.A graph G is fractional independentset-deletable k-factor-critical(in short,fractional ID-k-factor-critical),if G I has a fractional k-factor for every independent set I of G.The binding number bind(G)of a graph G is defined as bind(G)=min|NG(X)||X|:=X V(G),NG(X)=V(G).In this paper,it is proved that a graph G is fractional ID-k-factor-critical if n≥6k 9 and bind(G)(3k 1)(n 1)kn 2k+2. 相似文献
70.
Junwye Lee Jonghyun Koo Si Un Hwang Sunmin Min Sang Jung Ahn Yonghan Roh Sung Ha Park 《Current Applied Physics》2012,12(4):1207-1211
We report the structural and functional stabilities of artificially synthesized DNA ultra-thin films. Fully covered DNA ultra-thin films on a silica substrate were fabricated by the silica-assisted growth method and those samples were then incubated in various chemicals and physical conditions. The DNA ultra-thin films showed high maintainability under those harsh conditions and these results would aid to facilitate the use of artificial DNA ultra-thin films in advanced research areas such as biophotonics and bioelectronics. 相似文献